Iron Unlock: Paving the Way to Affordable Green Hydrogen

The pursuit of solutions to global climate change has led scientists to explore innovative ways to reduce our dependence on fossil fuels. Amid the myriad challenges facing the world, cleaner, sustainable alternatives to difficult-to-resistance areas such as steel production, chemical manufacturing, aviation and international transportation have been found. These industries are on the cusp of transformation, green hydrogen (generated through water electrolysis using renewable energy) to play a key role. Alkaline water electrolysis (AWE) is a technology that uses nickel (Ni) and iron (Fe) instead of rare precious metals (rare precious metals), and it is one of the most promising methods for large-scale green hydrogen production. Recent advances have focused on improving the efficiency of AWE, laying the foundation for the sustainable energy revolution by minimizing the energy required while maximizing output.
In a groundbreaking study led by Dr. Maximilian Demnitz, collaborated with Yuran Martins Lamas, Rodrigo Lira Garcia Barros, Anouk de Leeuw den Bouter, Professor John van der Schaaf and Dr. Matheus theodorus theodorus de Groot. Published in Iscience, a new method of hydrogen production has been revealed, marking a significant step in sustainable energy research. By integrating iron into the electrolytes of alkaline water electrolytic systems, the team not only demonstrates an innovative approach to producing hydrogen, but also sheds light on a path to reduce our dependence on fossil fuels.
This creative study not only hopes to improve the efficiency and viability of hydrogen production, but also aligns with global efforts to transition to more sustainable energy solutions. Integrating iron into the electrolysis process is a catalyst that promotes a more efficient and cost-effective approach to producing hydrogen. This breakthrough is particularly influential for sectors striving to transition from traditional fossil fuels to green alternatives.
The findings of this study show that the presence of iron in the electrolyte significantly enhances the electrolysis process, making hydrogen production not only more efficient, but also more feasible in large-scale applications. This coincides with the global efforts toward renewable energy and the urgent need to find sustainable alternatives to fossil fuel consumption. “Including electrolyte iron acts as a catalyst, speeding up the hydrogen production process without the need for expensive and scarce materials or complex catalyst designs were previously considered essential,” explains Dr. Demnitz. In summary, Dr. Demnitz, Technical University of Eindhoven, has accelerated the hydrogen production process. The work of his colleagues is a beacon of innovation in the field of sustainable energy. Their research on enhancing alkaline water electrolysis by adding electrolyte iron is not only a technical achievement. This is a step towards a cleaner and more sustainable future. Their discovery is expected to accelerate the transition to green hydrogen, making it the cornerstone of our renewable energy landscape.
Journal Reference
Demnitz, M. wait. “The effect of the addition of iron on the electrolyte on the electrolytic properties of alkaline water.” Iscience, 27(1), 108695, 2023. doi: https://doi.org/10.1016/j.isci.2023.108695.
About the Author
Thijs de Groot He is an associate professor in the field of electrochemical process technology. He conducted research on the production of green hydrogen through water electrolysis, focusing on basic and anion-exchange membrane electrolysis. His research focuses on improving the productivity and flexibility of these electrolytics, focusing on improving cell design, the effects of bubbles and supersaturation, the transport of ions and gases, and the use of advanced electrochemical technologies such as electrochemical barrier spectroscopy.
Thijs de Groot has worked in the electrochemical industry for over 15 years and has a good understanding of the challenges involved in developing and amplifying the electrochemical process.

Maximilian Demnitz Background is located in the fields of inorganic and thermodynamic chemistry. For postdoctoral studies, he extends his research to electrochemistry.
“Improving the performance of electrolytes and understanding the science behind it is a key aspect of a rapidly growing and thriving hydrogen economy.
Therefore, my research focuses on two aspects:
1) Enhance the separator and cellular components used in alkaline water electrolysis to show lower resistance, smaller gas crossover and involvement in the catalytic reaction of H2 and o2 Production.
To do this, we modified the diaphragm using a (catalytic) coating and tested the diaphragm (CCD) with catalyst coated diaphragm in the electrolyte. To this end, we further improved the membrane electrode assembly in the cells to show optimal performance and long-term stability.
2) Understand and evaluate the role of dopants in electrolyte performance. Here, FE is of particular interest because it can significantly improve electrolytic performance. Furthermore, focus will be on vanadium-doped electrolytes that have been shown to stabilize the long-term performance of the electrodes. ”